2005

Hydrogenation of olefins over hydrotreating catalysts. Promotion effect on the activity and on the involvement of H2S in the reaction.
M. BREMAUD, L. VIVIER, G. PEROT, V. HARLE and C. BOUCHY
Applied Catalysis A : General, 289, 44-50 (2005).

On the hydrodesulfurization of FCC gasoline : a review.
S. BRUNET, D. MEY, G. PEROT, C BOUCHY, F. DIEHL,
Applied Catalysis A : General, 278, 143-172 (2005).

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2004

HDS of a model FCC gasoline over a sulfided CoMo/Al2O3 catalyst. Effect of the addition of potassium.
D. MEY, S. BRUNET, C. CANAFF, G. PEROT, F. MAUGE, C. BOUCHY, F. DIEHL,
Journal of Catalysis, 227, 425-436 (2004).

Activation of alumina-supported hydrotreating catalysts by organosulfides - Comparison with H2S and effect of different solvents.
S. TEXIER, G. BERHAULT, G. PÉROT, V. HARLÉ, F. DIEHL,
Journal of Catalysi, 223, 404-418 (2004).

Effect of acridine and of octahydroacridine on the HDS of 4,6-dimethyldibenzothiophene catalysed by sulfided NiMoP/Al2O3.
V. RAKOTOVAO-RABARIHOELA, S. BRUNET, G. BERHAULT, G. PEROT, F. DIEHL,
Applied Catalysis A: General, 267, 17-25 (2004).

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2003

Catalytic Deep HDS of Model FCC Feed over a CoMo/Al2O3 Catalyst Modified by Potassium.
D. MEY, S. BRUNET, G. PEROT, F. DIEHL,
Preprints - American Chemical Society, Division of Fuel Chemistry, 48(1), 44-45 (2003).

Hydrogenation of Propene on Sulfide Catalysts – H-D Isotopic Study.
M. BREMAUD, L. VIVIER, G. PEROT, V. HARLE,
Preprints - American Chemical Society, Division of Fuel Chemistry, 48(1), 129-130 (2003).

Activation of Hydrogen over Sulfide Catalysts. Relevance to Kinetics and Mechanisms of Hydrotreating Reactions.
G. PEROT,
Preprints - American Chemical Society, Division of Fuel Chemistry, 48(1), 127-128 (2003).

Hydrotreating catalysts containing zeolites and related materials – Mechanistic aspects related to deep desulfurization.
G. PEROT,
Catalysis Today, 86, 111-128 (2003).

Deep hydrodesulfurization : Reactions and catalysts.
M. BREYSSE, C.E. HEDOIRE, C. LOUIS, G. PEROT,
Studies in Surface Sciences ans Catalysis, 145, 115-120 (2003).

Cobalt-Molybdenum sulfide catalysts prepared by in situ activation of bimetallic (Co-Mo) alkylthiomolybdates.
H. NAVA, C. ORNELAS, A. AGUILAR, G. BERHAULT, S. FUENTES, G. ALONSO,
Catalysis letters, 26, 257-265 (2003).

Mesoporous Carbon-containing MoS2 materials formed fram the in situ decomposition of tetraalkylammonium thiomolybdates.
G. ALONSO, G. BERHAULT, F. PARAGUAY, E. RIVIERA, S. FUENTES, R.R. CHIANELLI,
Materials Research Bulletin, 38, 1045-1055 (2003).

Deep desulfurization : Reactions, catalysts and technological challenges.
M. BREYSSE, G. DJEGA-MARIADASSOU, S. PESSAYRE, C. GEANTET, M. VRINAT, G. PEROT, M. LEMAIRE,
Catalysis Today, 84, 129-138 (2003).

Hydrotreating catalysts containing zeolites and related materials - Méchanistic aspects related to deep desulfurization.
G. PEROT,
Catalysis Today, 86,111-128 (2003).

Comparative study of WS2 and Co(Ni)/WS2 HDS catalysts prepared by ex situ/in situ activation of ammonium thiotungstate.
J. ESPINO, L. ALVAREZ, C ORNELAS, JL RICOS, S. FUENTES, G. BERHAULT, G ALONSO,
Catalysis letters, 90, 71-80 (2003).

Metal suldides.
G. BERHAULT, RR CHIANELLI,
Encyclopêdia of Catalysis, I. Horvath ed. vol. 4, 694-725 (2003).

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2001

Characterization of the balance between metallic and acidic properties of Cu-MFI catalysts by using the transformation of haloaromatic compounds. Effect of copper loading and Si/Al ratio.
S. VOL, L. VIVIER, G. PEROT,
Journal of Molecular Catalysis A : Chemical, 172, 241 (2001).

Involvement of support hydrogen in the H2-D2 isotopic exchange on sulfide catalysts.
A. SCAFFIDI, L. VIVIER, A. TRAVERT, F. MAUGE, S. KASZTELAN, C. SCOTT, G. PEROT,
Studies in Surface Science and Catalysis, 138, 31 (2001).

The Fries rearrangement.
M. GUISNET, G. PEROT,
Fine Chemicals through Heterogenous Catalysis. R.A. Sheldon and H. van Bekkum eds., pp. 211-216 (2001).

Transformation of ketones over sulfided CoMo/Al2O3 catalyst - Factors affecting thiol selectivity.
J. MIJOIN, C. POMMIER, F. RICHARD, G. PEROT,
Journal of Molecular Catalysis A : Chemical, 169, 171 (2001).

Mechanistic considerations on the involvement of dihydrointermediates in the hydrodesulfurizatrion of dibenzothiophene-type compounds over molybdenum sulfide catalysts.
J. MIJOIN, G. PEROT, F. BATAILLE, J.L. LEMBERTON, M. BREYSSE, S. KASZTELAN,
Catalysis Letters, 71, 139 (2001).

Tetralin hydrogenation catalyzed by Mo2C/Al2O3 adn WC/Al2O3 in the presence of H2S.
P. DA COSTA, J.L. LEMBERTON, C. POTVIN, J.M. MANOLI, G. PEROT, M. BREYSSE, G. DJEGA-MARIADASSOU,
Catalysis Today, 65, 195 (2001).

New aspects of the catalytic functions on sulfide catalysts.
M. BREYSSE, G. BERHAULT, S. KASZTELAN, M. LACROIX, F. MAUGE, G. PEROT,
Catalysis Today, 66, 15 (2001).

Sulfided Mo and CoMo supported on zeolite as hydrodesulfurization catalysts : transformation of dibenzothiophene and 4,6-methyldibenzothiophene.
F. BATAILLE, J.L. LEMBERTON, G. PEROT, P. LEYRIT, T. CSERI, N. MARCHAL, S. KASZTELAN,
Applied Catalysis A : General, 220, 191 (2001).

Kinetic modeling of the effect of H2S and of NH3 on toluene hydrogenation in the presence of a NiMo/Al2O3 hydrotreating catalyst. Discrimination between homolytic and heterolytic models.
S. BLANCHIN, P. GALTIER, S. KASZTELAN, S. KRESSMANN, H. PENET, G. PEROT,
Journal of Physical Chemistry A, 105, 10860 (2001).

Synthesis and characterization of tetraalkylammonium thiomolybdates and thiothungstates in aqueous solution.
G. ALONSO, G. BERHAULT, R.R. CHIANELLI,
Iorganica Chimica Acta, 316, 105 (2001).

Ion mediation and surface charge density in phase transition of micelle templated silica.
B. ECHCHAHED, M. MORIN, S. BLAIS, A.R. BADEI, G. BERHAULT, L. BONNEVIOT,
Microporous and Mesoporous Materials, 44-45, 53 (2001).

Evolution of the surface sulfur composition of a Ru sulfide particle during CH3SH condensation reaction : sulfur migration from the bulk to the surface.
G. BERHAULT, M. LACROIX,
New Journal of Chemistry, 25, 308 (2001).

The role of strutural carbon in transition metal sulfides hydrotreating catalysts.
G. BERHAULT, A. MEHTA, A.C . PAVEL, J. YANG, L. RENDON, M.J. YACAMAN, LC. ARAIZA, A.D. MOLLER, R.R. CHIANELLI,
Journal of Catalysis, 198, 9 (2001).

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2000

Alkyldibenzothiophenes hydrodesulfurization-Promoter effect, reactivity, and reaction mechanism.
F. BATAILLE, J.L. LEMBERTON, P. MICHAUD, G. PEROT, M. VRINAT, M. LEMAIRE, E. SCHULZ, M. BREYSSE, S. KASZTELAN,
Journal of Catalysis, 191, 409 (2000).

Influence of sulfur containing compounds on high temperature coke formation on hydrotreating catalyst.
R. LEBRETON, S. BRUNET, G. PEROT, V. HARLE, S. KASZTELAN,
Studies in Surface Science and Catalysis, 130, 2861 (2000).

Selective promoting effect on alkyldibenzothiophenes hydodesulfurization pathways.
F. BATAILLE, J. MIJOIN, J.L. LEMBERTON, G. PEROT, G. BERHAULT, M. LACROIX, F. MAUGE, S. KASZTELAN, M. BREYSSE,
Studies in Surface Science and Catalysis, 130, 283 (2000).

Formation of sulfur-containing compounds under Fluid Catalytic Cracking reaction conditions.
P. LEFLAIVE, J.L. LEMBERTON, G. PEROT, C. MIRGAIN, J.Y. CARRIAT, J.M. COLIN,
Studies in Surface Science and Catalysis, 130, 2465 (2000).

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1999

Deuterium tracer studies on hydrotreating catalysts. 3. Influence of nickel on the rates of H2-D2 and H2S-D2 isotopic exchange.
C. THOMAS, L. VIVIER, M. LESCANNE, S. KASZTELAN, G. PEROT,
Catalysis Letters, 58, 33 (1999).

Thioreduction of cyclopentanone and hydrodesulfurization of dibenzothiophene over sulfided nickel or cobalt-promoted molybdenum on alumina catalysts.
J. MIJOIN, V. THEVENIN, N. GARCIA AGUIRE, H. YUZE, J. WANG, W.Z. LI, G. PEROT, J.L. LEMBERTON,
Applied Catalysis A : General, 180, 95 (1999).

Deactivation and characterization of hydrotreating NiMo/Al2O3 catalyst coked by anthracene.
R. LEBRETON, S. BRUNET, G. PEROT, V. HARLE, S. KASZTELAN,
Studies in Surface Science and Catalysis, 126, 195 (1999).

Reactivity of antimony mixed halides for the fluorination of the tetracholrethene (PCE) in liquid phase.
S. BRUNET, C. BATIOT, P. MORICEAU, N. THYBAUD,
Journal of Molecular Catalysis, 142, 233 (1999).

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Representative Publications

he reactions involved in hydrodenitrogenation.
G. PEROT,
Catalysis Today, 10, 447-472 (1991).

Properties of Chromium (III) oxides involved in the catalytic gas phase fluorination of CF3CH2Cl.
S. BRUNET, B.BOUSSAND AND D.MARTIN,
Journal of Catalysis, 171, 287-292 (1997).

Deuterium tracer studies on hydrotreating catalysts 2. Contribution of the alumina support to H-D exchange.
C. THOMAS, L. VIVIER, A. TRAVERT, F. MAUGE, S. KASZTELAN and
G. PEROT,
Journal of Catalysis, 179 (2), 495-502 (1998).

Zeolithe-catalysed acylation of heterolytic compounds - VI. One step synthesis of 3-(benzofuran-2-carbonyl)pentane-2,4-dione from 2-acetylbenzofuran over HY-zeoltihe.
F. RICHARD, H. CARREYRE, J.M. COUSTARD, C. BACHMANN and G. PEROT,
Tetrahedron, 54-49, 14757-14766 (1998).

Influence of the Morphology and of the composition of chromium oxides on their catalytic activity for the gas phase fluorination of 1,1,1-trifluoro-2-chloro-ethane. Preparation of hydrofluorocarbons.
S. BRUNET, B. BOUSSAND, A. ROUSSET and D. ANDRE,
Applied Catalysis A : General, 168, 57-61 (1998).

Reactivity of antimony mixed halides for the fluorination of the Tetrachlorethene (PCE) in liquid phase.
S. BRUNET, C. BATIOT, P. MORICEAU AND N. THYBAUD,
:Journal of Molecular Catalysis, 142, 233-236 (1999).

Alkyldibenzothiophenes hydrodesulfurization - Promoter effect, reactivity and reaction mechanism.
F. BATAILLE, J.L. LEMBERTON, P. MICHAUD, G. PEROT, M. VRINAT, M. LEMAIRE, E. SCHULZ, M. BREYSSE and S. KASZTELAN,
Journal of Catalysis, 191, 409-422 (2000).

Kinetic modeling of the effect of H2S and of NH3 on toluene hydrogenation in the presence of a NiMo/Al2O3 hydrotreating catalyst. Discrimination between homolytic and heterolytic models.
S. BLANCHIN, P. GALTIER, S. KASZTELAN, S. KRESSMANN, H. PENET, G. PEROT,
Journal of Physical Chemistry A, 105, 10860-10866 (2001).

On the origin of sulfur impurities in fluid catalytic cracking gasoline - reactivity of thiophene derivatives and of their possible precursors under FCC conditions.
P. LEFLAIVE, J.L. LEMBERTON, G. PEROT, C. MIRGAIN, J.Y. CARRIAT, J.M. COLIN,
Applied Catalysis A : General, 227, 201-215 (2002).

Catalytic deep HDS of model molecules contained in FCC gasoline over CoMo/Al2O3 catalyst.
D. MEY, S. BRUNET, G. PEROT, F. DIEHL, S. KAZSTELAN,
Am.Chem.Soc.prepr.div.petrol.chem, 47, 69-72 (2002).

Hydrogen activation by transition metal sulfides.
M. BREYSSE, E. FURIMSKY, S. KASZTELAN, M. LACROIX, G. PEROT,
Catalysis Reviews and Science Engineering 44 (4), 651-735 (2002).

Hydrotreating catalysts containing zeolites ans related materials - Mechanistic aspects related to deep desulfurization.
G. PEROT,
Catalysis Today, 84, 129-138 (2003).

Activation of alumina-supported hydrotreating catalysts by organosulfides - Comparison with H2S and effect of different solvents.
S. TEXIER, G. BERHAULT, G. PEROT, V. HARLE, F. DIEHL,
Journal of Catalysis, 223, 404-418 (2004).

On the hydrodesulfurization of FCC gasoline : a review.
S. BRUNET, D. MEY, G. PEROT, C. BOUCHY, F. DIEHL,
Applied Catalysis A : General, 278, 143-172 (2005).

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